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This was in part because short prime commercial paper could be rediscounted at the newly organized Federal Reserve Banks and security loans could not, and in part because the volume of call loans grew enormously in the late 1920s and the volume of commercial paper did not Corporations in the United States, as in Britain, tended then to borrow more against lines of credit at their own banks and less in the commercial paper market In the 1930 s, both the commercial paper market and the call loan market shrank in significance Call loans never recovered their importance, partly because of strict margin-requirement rules Treasury bills, however, have dominated the money markets both here and abroad since the 1930 s.

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The approach of synthesizing a monomer containing the desired functional group followed by (co)polymerization can be illustrated for the poly[4(5)-vinylimidazole] catalyst (VII) described in Sec. 9-1j. Synthesis involves the sequence of reactions starting from histidine (XXXVII) to yield 4(5)-vinylimidazole (XXXVIII), which is subsequently polymerized by radical initiation [Overberger and Vorchheimer, 1963].

9-67

FIGURE 31-4: Use a multiposition rotary switch to select crystals and therefore expand frequency coverage for your DH 100 Hyper Sax.

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Their rates in the 1930 s fell far below those of other short-term credit forms, sometimes to negative yields when investors or institutions wanted to report money at work rather than idle balances At the beginning of the century, commercial paper rates were high by pre-1970 standards, and call money rates, while very volatile, were also often high Before the establishment of the Federal Reserve System, it was not unusual for commercial paper to run up to 18 or 36% for a few days and for call money briefly to exceed 100% The average of four- to six-month commercial paper rates actually declined from the first decade of the century to the second and from the second decade to the third Call money rates also declined from the first decade to the second, but rose in the third decade.

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The key to the utility of this approach is whether the required functional group can be incorporated into a monomer that undergoes polymerization. Two methods have been used. One is the synthesis of a unique monomer such as 4(5)-vinylimidazole that contains the required functional group with an attached polymerizable linkage. The second method involves the incorporation of the required group as part of one of the more common types of monomers. The most successfully employed have been functional derivatives of acrylic and methacrylic esters and styrene where the functional group is part of the ester group and aromatic ring, respectively. Monomers suitable for step polymerizations have been much less frequently employed. 9-11a-3 Comparison of the Two Approaches

The two approaches are complementary. The functionalization of a polymer may be more advantageous for a particular system due to the availability of the appropriate polymer and the ease of accomplishing the required functionalization reaction in high yield with a minimum of side reactions. It may be completely unsuitable for a system where the appropriate polymer is not readily available and/or the required functionalization reaction does not proceed cleanly to high yield. The polymerization of a functional monomer will be advantageous for a system if synthesis of the required monomer can be accomplished in high yield and purity and polymerization or copolymerization proceeds to yield a high polymer of the required mechanical strength with good thermal and chemical resistance. The approach may be impractical if either monomer synthesis or polymer formation does not proceed satisfactorily. For any speci c polymer reagent, catalyst, or substrate, one approach may be more suitable than the other. The functionalization of polymer approach is used much more often than the functionalization of monomer approach at present because functional polymers such as chloromethylated polystyrene are readily available with different porosities and degrees of chloromethylation. There are relatively few situations where less work is needed to use the functionalization of monomer approach. Also, many practitioners of polymer reagents,

catalysts, and substrates are organic chemists, not polymer chemists, and there is a hesitancy in performing polymerization reactions. 9-11b Advantages of Polymer Reagents, Catalysts, and Substrates

In contrast, one-year prime corporate bond yields rose with long-term bond yields during the first and second decades, but rose even further during the third decade These contrasts are probably largely explained by the fact that the new Federal Reserve System helped the commercial paper market more than it helped these other short markets..

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